Q4. Give the IUPAC name of HOCH2CH2CH(OH)CH3.
Four carbons, –OH on C1 and C3 when numbered from the CH2OH end (the set {1, 3} beats {2, 4}); the “e” stays: butane-1,3-diol (NCERT page 196; reasoned).
Q5. Give the common and IUPAC names of CH3CH2CH2OCH(CH3)CH2CH3.
Common name: sec-butyl propyl ether (groups in alphabetical order). IUPAC name: the larger group, the four-carbon sec-butyl, is the parent butane, with propoxy on its C2: 2-propoxybutane (reasoned from NCERT page 198).
Q6. Name the phenol with –OH and –NO2 on adjacent ring carbons, by IUPAC and by its common ortho name.
2-Nitrophenol, o-nitrophenol: phenol is the parent, with –OH on C1 and –NO2 on C2 (reasoned from NCERT pages 196–197).